Science and Mathematics Faculty Publications

Title

A Novel Tin (II) Dithioether Complex

Document Type

Article

Publication Date

4-1-2006

Journal Title

Journal of Organometallic Chemistry

Volume

691

Issue

8

First Page

1658

Last Page

1659

Abstract

Organotin and related tin containing compounds are a recurring motif in organometallic chemistry. Here we report a new complex resulting from the reaction of tin (II) chloride with a dithioether diallyl ether ligand created as a side product from other research in our lab. This new complex is reasonably stable and can be synthesized on the bench top with no extraordinary measures required to exclude air or moisture. Its crystal structure reveals a five coordinate pseudo-square pyramidal geometry around tin, with the ligand binding the metal through its thioether sulfurs and the chlorides bridging.

Keywords

Thioether, Sulfide, Tin (II) complex, 119Sn NMR

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