Monomeric Group 13 Compounds with Bidentate (N,O) Ligands

Authors

Michael S. Hill
Aaron R. Hutchison, Cedarville UniversityFollow
Timothy S. Keizer
Sean Parkin
Michael A. VanAelstyn
David A. Atwood

Document Type

Article

Publication Date

5-15-2001

Journal Title

Journal of Organometaliic Chemistry

Volume

628

Issue

1

First Page

71

Last Page

75

Abstract

The bidentate ligand, Sal(^tBu)H, is prepared by the condensation of one equivalent of a bulky amine with 3,-5-di-tert-butylsalicylaldehyde. When one equivalent of Sal(^tBu)H is added to MR₃ or AlMe₂Cl, compounds are btained which have the general form: [Sal(^tBu)MR₂] (with M/R combinations, Al/Me (1), Al/Et (3), Ga/Et (4) and In/Et (5)) and Sal(^tBu)AlMeCl (2). The compounds are characterized by melting point, elemental analyses, IR, ¹H-NMR, and in the case of 2 and 3 by single-crystal X-ray analysis.

Keywords

Aluminum, gallium, chelate

Recommended Citation

Atwood, D. A., Hill, M. S., Hutchison, A. R. , Keizer, T. S. , & Parkin, S. (2001). Monomeric Group 13 compounds with bidentate (N,O) ligands. Journal of Organometaliic Chemistry, 628 (1), 71-75.